Green Chemistry @ MUN


Summer Schools, Publications, and Conferences with the Green Cat Chem Crew! ☀️⛱️🍋‍🟩
August 26, 2025, 4:35 pm
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There has been lots of exciting news from the Green Cat Chem group over the last few months! Let’s begin by congratulating everyone on successfully publishing multiple manuscripts! 🎉

Publications

  1. F. M. Kerton, “Applying the principles of green chemistry to achieve a more sustainable polymer life cycle,” Current Opinion in Green and Sustainable Chemistry, 2025, 51, 100996. (DOI: https://doi.org/10.1016/j.cogsc.2024.100996)
  2. K. V. M. Hanrahan, C. M. Meyers, C. W. Vos, J.-B. Lin and C. M. Kozak, “Kinetic studies of zirconium-catalyzed ring-opening copolymerization of epoxide and cyclic anhydride,” Canadian Journal of Chemistry, 2025, e-First. (DOI: https://doi.org/10.1139/cjc-2024-0201)
  3. S. Boudreau, S. Hrapovic, E. McIsaac, E. Lam, F. Berrué and F. M. Kerton, “Transforming waste fish bones into nanoparticles with ultrasound and aqueous organic acids,” RSC Sustainability, 2025, 3, 2325-2332. (DOI: 10.1039/D5SU00164A)
  4. O. N. Egbe, B. H. P. Morrissey, F. M. Kerton and T. J. Stockmann, “Anodic expulsion of Cu nanoparticles from a polycrystalline Cu substrate: a novel corrosion and single entity study approach,” Nanoscale, 2025, 17, 10609-10619. (DOI: 10.1039/D4NR04863F)
  5. J. N. Murphy, M. A. Morgan, S. Christian-Robinson, M. M. Fitzgerald and F. M. Kerton, “Optimized process to produce calcium acetate from waste blue mussel shells and its use as a de-icer,” Canadian Journal of Chemistry, 2025, e-First. (DOI: https://doi.org/10.1139/cjc-2024-0279)
  6. S. Christian-Robinson, F. Kong, E. B. Easton and F. M. Kerton, “Modification of calcium carbonate from blue mussel shells with copper oxide nanoparticles,” RSC Sustainability, 2025, 3, 3009-3018. (DOI: 10.1039/D5SU00188A)
  7. M. D. Wheeler and F. M. Kerton, “Borane-catalysed cyclodepolymerization of CO2-derived polycarbonates”, Faraday Discussions, 2025, Accepted Manuscript. (DOI: 10.1039/D5FD00050E)
  8. J. E. Peddle, C. M. Laprise, M. D. Wheeler, M. M. Fitzgerald, F. M. Kerton and C. M. Kozak, “Ocean Biomass-derived Feedstocks for Non-Isocyanate Polyurethane Synthesis,” Faraday Discussions, 2025, Accepted Manuscript. (DOI: 10.1039/D5FD00059A)
  9. M. J. J. Laprade, K. N. Robertson, J. A. C. Clyburne and C. M. Kozak, “A new class of ligand derived from the reactions of bis(dialkylphosphino)amines and 9-diazofluorene: preparation, structure and reactivity,” Dalton Transactions, 2025, 54, 11382-11397. (DOI: 10.1039/D4DT03402C)

Conferences & Summer Schools

Many students from Green Cat Chem had the privilege to present at several conferences and attend summer schools during the past few months. Throughout May and June, Prof. Kerton and Prof. Kozak attended multiple conferences, including the Commonwealth Chemistry Congress in South Africa, the International Conference on Sustainable Chemistry for Net Zero in Scotland, the RSC Sustainability Symposium in England, and the Gordon Research Conference on Biobased Chemicals and Materials in Maine.

At the CSC Conference this year in Ottawa, Prof. Kerton and Prof. Kozak had the opportunity to present their research as well as many of their students, including Sarah Boudreau, Cyler Vos, Amy Mitchell, Megan Graham, Meghan McKeeman, Mikhailey Wheeler, Olivia Wyper, Megan Fitzgerald, and Emily Wiseman.

Prof. Kerton, Prof. Kozak, Sarah, Mikhailey, and Olivia presented at the ACS Green Chemistry & Engineering Conference in Pittsburgh, PA. Before the conference officially started, Olivia took part of a service project in North Pittsburgh neighbourhoods and helped organized Beyond Benign’s Green Chemistry Committment summit with Mikhailey and other international students. At this summit, Prof. Kerton was invited to give a short presentation. At the awards banquet on the first evening, Sarah accepted the Joseph Breen Memorial Fellowship from the ACS GCI.

Prof. Kerton, the chair of the Committee on Chemical Research Applied to World Needs (CHEMRAWN), represented Canada at IUPAC2025 in Kuala Lumpur, Malaysia. Not only did she present at the CHEMRAWN Meeting and represented Canada at the IUPAC Council Meeting, but she was also at the World Chemistry Leadership Meeting and she was a keynote speaker in the symposium “Towards a Sustainable Future: Engaging Society for a Systemic Change”. Prof. Kerton will be the chair of IUPAC2027 in Montreal, QC which will be held in conjunction with CSC 2027. We look forward to it!

Sarah travelled to Burlington, VT for the ACS GCI Green & Sustainable Chemistry Summer School from July 26 to August 1, 2025. During this year’s summer school, multiple green chemistry topics were explored including metrics, green solvents, earth-abundant catalysis, renewable feedstocks, circularity, molecular design, and designing safer chemicals for healthy communities. She presented two research posters and a group presentation on 6PPD.

Mikhailey, Emily, Meghan, and Oforbuike Egbe attended the Centre for Innovation and Research on Carbon Utilization in Industrial Technologies (CIRCUIT) Summer School in Quebec City, QC where they presented research posters and learned about electrochemical CO2 systems, applications of AI models, and current achievements in CO2 electrolyzers.

We now all look forward to a productive start to the Fall semester next month, and hope everyone gets the opportunity to enjoy the last few weeks of Summer! 😎



Catalysis Science and Technology Selects Hua’s paper as a “Hot Article”

The RSC journal Catalysis Science and Technology has selected our paper on Cr-catalyzed CO2/epoxide copolymerization as a “Hot Article” for January. The paper describes work performed by Hua Chen during her M.Sc. studies with Dr. Kozak. Thank you Hua for your hard work on this paper and thanks to Louise Dawe, whose ninja-like crystallographic skills were vital to solving the structure of one of the catalysts discussed in the paper. Access to the article can be found here.

GA



Group Meeting, September 2013
September 25, 2013, 10:31 pm
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Group Meeting, September 2013

Green Chemistry and Catalysis Group Meeting 🙂



Another former GCCG grad student receives exciting news!
June 5, 2013, 1:24 pm
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Xin Qian (M.Sc. in the Kozak group) has been notified that she is a finalist in the 2013 Reaxys PhD Prize! Having completed her M.Sc. at MUN, Xin is pursuing a PhD at Ecole Polytechnique in Paris (with Corinne Gosmini) and will begin a PDF in the Department of Materials at Oxford University in October. Congratulations Xin!

Xin



Angela Crane (formerly of Kozak group) – TV star in Vancouver :)
May 2, 2013, 6:11 pm
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Congratulations to former student
March 28, 2013, 5:25 pm
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Congratulations to Marcus Drover for being awarded a Vanier CGS award. This means he was ranked as one of the top new doctoral graduate students in any discipline (science, engineering, health/medicine, social sciences and humanities) across Canada! These scholarships are valued at $50,000 per year for three years…..don’t forget to save some of those funds for during a future postdoc, Marcus! 😉 and good luck with your current research.

Marcus is currently pursuing graduate studies in chemistry at UBC under the supervision of Prof. Jen Love and Prof. Laurel Schafer.

He graduated from MUN with a BSc (Hons) degree in 2012. He performed research with several supervisors during his time here. He held SWASP and MUCEP positions in Dr. Kerton‘s group during 2010 (studying Aluminum coordination chemistry). He also worked with Dr. Pansare on organic chemistry in summer 2010 too (Canada Summer Jobs). In summer 2011, after his 3rd year at MUN, he worked in Dr. Kerton‘s group again – this time on biomass conversion – whilst being supported by an NSERC USRA. During the academic year 2011/2012, he worked in Dr. Kerton’s group in collaboration with Dr. Celine Schneider, studying Li and Bi coordination chemistry, and both solution and solid-state multinuclear NMR spectroscopy. An image based on his honours project was selected for inclusion in the student calendar of the Inorganic Division, Chemical Institute of Canada. In summer 2012, he had a second NSERC USRA award and worked with Prof. Laurie Thompson on coordination complexes and supramolecular assembly.

Publications which Marcus co-authored during his time in the Kerton group include:

1. M. W. Drover, K. W. Omari, J. N. Murphy and F. M. Kerton*, “Formation of a renewable amide via direct conversion of N-acetyl-D-glucosamine”, RSC Adv., 2012, 2, 4642-4643,  DOI:10.1039/C2RA20578E

graphicalabstract

Graphical Abstract from RSC Advances paper (2012) – First Author, Marcus Drover

2. N. Ikpo, S. Barbon, M. Drover, L. N. Dawe and F. M. Kerton*, “Aluminum methyl and chloro complexes bearing monoanionic aminephenolate ligands: synthesis, characterization and use in polymerizations”, Organometallics, 2012, 31,  8145-8158, http://dx.doi.org/10.1021/om300757u

3. M. Drover and co-authors, Lithium complexes of amine-phenolate ligands, Manuscript in preparation.

4. M. Drover and co-authors, Bismuth complexes of amine-phenolate ligands, Manuscript in preparation.



Carbon Dioxide Copolymerization by Aluminum Catalysts – Perspective/Review Published

Fran, Nduka (PhD 2008-2013) and Jenna (PhD 2011-2015) wrote a short review article on copolymerization of carbon dioxide with epoxides late last year and early this year. It has been accepted for publication in a special issue of Dalton Transactions on the topic of “Advances in Metal-Catalysed Polymerisation and Related Transformations”. Although Aluminum catalysts are generally less-reactive than some state of the art catalysts for such reactions, there is significant scope to develop new systems based on this cheap metal. For example, Aluminum can catalyse many different types of polymerization reactions and so one could imagine preparing terpolymers (polymers made up of 3 different sub-units/monomers) or even more complex materials.

Here is a link to the article: http://pubs.rsc.org/en/content/articlelanding/2013/dt/c3dt00049d

Graphical Abstract for Perspective on Al catalysts for carbon dioxide-epoxide copolymerizations

Graphical Abstract for Perspective on Al catalysts for carbon dioxide-epoxide copolymerizations



Congratulations Jen
February 11, 2013, 4:14 pm
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…on your award (1st place!) at the 20th annual Chemistry Colloquium Contest! Sorry we didn’t post this sooner but we were waiting for a departmental press release first.



Congratulations to Marcus, Khaled and Jen!
March 29, 2012, 2:43 pm
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Their manuscript has just been accepted for publication in RSC Advances. (This is a new interdisciplinary journal of the Royal Society of Chemistry)

RSC Adv., DOI:10.1039/C2RA20578E

Khaled is a PhD candidate in the MUN Green Chemistry & Catalysis Group. Marcus obtained his results during an NSERC USRA in the group during summer 2011 and Jen held a SWASP position in the group at the same time.



Article in “The Scope” features the Green Chemistry and Catalysis Group

The St. John’s arts and entertainment magazine, “The Scope”, recently published an article in their on-line edition on some of the work occurring in the MUN Green Chemistry and Catalysis Group. Entitled “Great future in green plastics“, the article by Dave Jerome describes the research on degradable plastics that is being performed by Justin Belanger and other students in the group.Image